The Nonequilibrium Thermodynamics of Small Systems

The interactions of tiny objects with their environment are dominated by thermal fluctuations. Guided by theory and assisted by micromanipulation tools, scientists have begun to study such interactions in detail.Comment: PDF file, 13 pages. Long version of the paper published in Physics Toda

A glass transition scenario based on heterogeneities and entropy barriers

We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in off-equilibrium supercooled liquids which leads to a natural definition of the complexity. From the absence of coarsening growth we can derive an entropy based fluctuation formula which relates the free energy dissipation rate in the glass with the nucleation rate of the largest cooperative regions. As by-product we obtain a new phenomenological relation between the largest relaxation time in the supercooled liquid phase and an effective temperature. This differs from the Adam-Gibbs relation in that predicts no divergence of the primary relaxation time at the Kauzmann temperature and the existence of a crossover from fragile to strong behavior.Comment: 8th International Workshop on Disordered Systems, Andalo (Trento), Italy, 12-15 March 200

Work distribution functions in polymer stretching experiments

We compute the distribution of the work done in stretching a Gaussian polymer, made of N monomers, at a finite rate. For a one-dimensional polymer undergoing Rouse dynamics, the work distribution is a Gaussian and we explicitly compute the mean and width. The two cases where the polymer is stretched, either by constraining its end or by constraining the force on it, are examined. We discuss connections to Jarzynski's equality and the fluctuation theorems.Comment: 5 pages, 2 figure

Intermittency of glassy relaxation and the emergence of a non-equilibrium spontaneous measure in the aging regime

We consider heat exchange processes between non-equilibrium aging systems (in their activated regime) and the thermal bath in contact. We discuss a scenario where two different heat exchange processes concur in the overall heat dissipation: a stimulated fast process determined by the temperature of the bath and a spontaneous intermittent process determined by the fact that the system has been prepared in a non-equilibrium state. The latter is described by a probability distribution function (PDF) that has an exponential tail of width given by a parameter $\lambda$, and satisfies a fluctuation theorem (FT) governed by that parameter. The value of $\lambda$ is proportional to the so-called effective temperature, thereby providing a practical way to experimentally measure it by analyzing the PDF of intermittent events.Comment: Latex file, 8 pages + 5 postscript figure

The disordered Backgammon model

In this paper we consider an exactly solvable model which displays glassy behavior at zero temperature due to entropic barriers. The new ingredient of the model is the existence of different energy scales or modes associated to different relaxational time-scales. Low-temperature relaxation takes place by partial equilibration of successive lower energy modes. An adiabatic scaling solution, defined in terms of a threshold energy scale \eps^*, is proposed. For such a solution, modes with energy \eps\gg\eps^* are equilibrated at the bath temperature, modes with \eps\ll\eps^* remain out of equilibrium and relaxation occurs in the neighborhood of the threshold \eps\sim \eps^*. The model is presented as a toy example to investigate conditions related to the existence of an effective temperature in glassy systems and its possible dependence on the energy sector probed by the corresponding observable.Comment: 24 pages, 11 figure

Dynamic force spectroscopy of DNA hairpins. II. Irreversibility and dissipation

We investigate irreversibility and dissipation in single molecules that cooperatively fold/unfold in a two state manner under the action of mechanical force. We apply path thermodynamics to derive analytical expressions for the average dissipated work and the average hopping number in two state systems. It is shown how these quantities only depend on two parameters that characterize the folding/unfolding kinetics of the molecule: the fragility and the coexistence hopping rate. The latter has to be rescaled to take into account the appropriate experimental setup. Finally we carry out pulling experiments with optical tweezers in a specifically designed DNA hairpin that shows two-state cooperative folding. We then use these experimental results to validate our theoretical predictions.Comment: 28 pages, 12 figure

Aging effects and dynamic scaling in the 3d Edwards-Anderson spin glasses: a comparison with experiments

We present a detailed study of the scaling behavior of correlations functions and AC susceptibility relaxations in the aging regime in three dimensional spin glasses. The agreement between simulations and experiments is excellent confirming the validity of the full aging scenario with logarithmic corrections which manifests as weak sub-aging effects.Comment: 6 pages, 6 figures. Previously appeared as a part of cond-mat/000554

Evidence of aging in mean-field spin glass models

We study numerically the out of equilibrium dynamics of the hypercubic cell spin glass in high dimensionalities. We obtain evidence of aging effects qualitatively similar both to experiments and to simulations of low dimensional models. This suggests that the Sherrington-Kirkpatrick model as well as other mean-field finite connectivity lattices can be used to study these effects analytically.Comment: 13 pages + 5 figures (upon request

Replica Field Theory for Deterministic Models: Binary Sequences with Low Autocorrelation

We study systems without quenched disorder with a complex landscape, and we use replica symmetry theory to describe them. We discuss the Golay-Bernasconi-Derrida approximation of the low autocorrelation model, and we reconstruct it by using replica calculations. Then we consider the full model, its low $T$ properties (with the help of number theory) and a Hartree-Fock resummation of the high-temperature series. We show that replica theory allows to solve the model in the high $T$ phase. Our solution is based on one-link integral techniques, and is based on substituting a Fourier transform with a generic unitary transformation. We discuss this approach as a powerful tool to describe systems with a complex landscape in the absence of quenched disorder.Comment: 42 pages, uufile with eps figures added in figures, ROM2F/94/1